Gas Phase (Water Vapor)
The gaseous phase of water is known
as water vapor (or steam) and is characterized by a transparent cloud. Water
also exists in a rare fourth state called supercritical fluid, which occurs only in extremely uninhabitable conditions.
When water achieves a specific critical temperature and a specific critical pressure (647 K and 22.064 MPa), the liquid and gas phases
merge into one homogeneous fluid phase that shares properties of both gas and
liquid.
3.13 Phase Diagram of Water
Water freezes to form ice, ice thaws
to form liquid water, and both water and ice can transform into the vapor
state. Phase diagrams help describe how wate changes states depending on the
pressure and temperature.
3.15
Note the
following key points on a phase diagram:
2. The triple point (TP), a well-defined coordinate where the curves
intersect, at which the three states of matter (solid, liquid, gas) exist at equilibrium with each
other.
3.
Well-defined
boundaries between solid and liquid, solid and gas, and liquid and gas. During
the phase transition between two phases (i.e, along these boundaries), the
phases are in equilibrium with each other.
3.16 The Polarity of Water
The polar nature of water is a particularly important feature
that contributes to the uniqueness of this substance. The water molecule forms
an angle with an oxygen atom at the vertex and hydrogen atoms at the tips. Because oxygen has a
higher electro negativity than hydrogen, the side of the molecule with the
oxygen atom has a partial negative charge. An object with such a charge
difference is called a dipole (meaning "two poles"). The oxygen end
is partially negative, and the hydrogen end is partially positive; because of
this, the direction of the dipole moment points from the oxygen toward the
center position between the two hydrogens. This charge difference causes water
molecules to be attracted to each other (the relatively positive areas are
attracted to the relatively negative areas), as well as to other polar
molecules. This attraction contributes to hydrogen bonding and explains many of
water's properties (including its ability to act as a solvent to many
substances).
A water molecule can form a maximum
of four hydrogen bonds by accepting two hydrogen atoms and donating two
hydrogen atoms. Although hydrogen bonding is a relatively weak attraction
compared to the covalent bonds within the water molecule itself (intermolecular
bonds), it is responsible for a number of water's physical properties. One such property is its relatively high melting and
boiling points; more energy is required to break the hydrogen bonds between
molecules in order to change to a higher energy phase.
3.18 THE PROPERTIES OF RIVER SAND
The
sample of water were taken at random from the sand heaps collected by the
contractors for constructional purpose, and may be regarded as fairly
representative.
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